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dc.contributor.authorPrasad, Narendra Jai
dc.contributor.authorMain, Lyndsay
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorMcAdam, C. John
dc.date.accessioned2010-07-04T23:37:54Z
dc.date.available2010-07-04T23:37:54Z
dc.date.issued2010
dc.identifier.citationPrasad, N., Main, L., Nicholson, B.K. & McAdam, C.J. (2010). 2-Ferrocenyl-substituted pyrylium ions from coupling of ethynylferrocene with cyclomanganated chalcones. Journal of Organometallic Chemistry, 695(17), 1961-1965.en_NZ
dc.identifier.urihttp://hdl.handle.net/10289/4086
dc.description.abstract2-Ferrocenyl-substituted pyrylium salts are produced when orthomanganated chalcones are reacted with ethynylferrocene in CCl4. When the reaction is carried out in benzene, intermediate ferrocenyl-substituted (η5-pyranyl)Mn(CO)3 species can be isolated which give the pyrylium cations on oxidation. The electrochemistry of the 2-ferrocenyl-pyrylium cations shows both oxidation (of the ferrocenyl) and reduction (of the pyrylium) processes, and the UV–visible spectra show a broad band at ca 680 nm which can be assigned to an intramolecular charge transfer transition.en_NZ
dc.language.isoen
dc.publisherElsevieren_NZ
dc.subjectpyrylium saltsen_NZ
dc.subjectferrocenylen_NZ
dc.subjectpyranyl complexen_NZ
dc.subjectelectrochemistryen_NZ
dc.title2-Ferrocenyl-substituted pyrylium ions from coupling of ethynylferrocene with cyclomanganated chalconesen_NZ
dc.typeJournal Articleen_NZ
dc.identifier.doi10.1016/j.jorganchem.2010.05.006en_NZ
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page1961en_NZ
pubs.elements-id35027
pubs.end-page1965en_NZ
pubs.issue17en_NZ
pubs.volume695en_NZ


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