Novel six-coordinate Aryl- and Alkyltin  complexes

dc.contributor.author	Lloyd, Nicholas C.
dc.contributor.author	Nicholson, Brian K.
dc.contributor.author	Wilkins, Alistair L.
dc.contributor.author	Thomson, Ralph A.
dc.date.accessioned	2010-10-20T21:08:37Z
dc.date.available	2010-10-20T21:08:37Z
dc.date.issued	2002
dc.identifier.citation	Lloyd, N.C., Nicholson, B.K., Wilkins, A.L. & Thomson, R. (2002). Novel six-coordinate Aryl- and Alkyltin complexes. Chemistry in New Zealand, 66(1), 53-54.	en_NZ
dc.identifier.uri	http://hdl.handle.net/10289/4709
dc.description.abstract	Organo-tin compounds have wide applications as pesticides and as intermediates for organic synthesis.¹ They are invariably Sn(IV) derivatives and are generally four-coordinate.² The mixed organo/chioro compounds of the type RnSnCI4-n do however have the ability to expand their coordination numbers to five or six. This depends critically on the substituents - with four organic groups, R₄Sn, there is no tendency at all to coordinate extra ligands, while at the other extreme SnCl₄ readily forms six-coordinate [SnC1₄L₂] complexes since the electronegative halo groups increase the Lewis acidity of the tin centre.	en_NZ
dc.format.mimetype	application/pdf
dc.language.iso	en
dc.publisher	New Zealand Institute of Chemistry	en_NZ
dc.relation.uri	http://nzic.org.nz/CiNZ/CiNZ.html	en_NZ
dc.rights	This article has been published in the journal: Chemistry in New Zealand. Used with permission.	en_NZ
dc.subject	chemistry	en_NZ
dc.title	Novel six-coordinate Aryl- and Alkyltin complexes	en_NZ
dc.type	Journal Article	en_NZ