Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl
Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl
Abstract
The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn ₂(thioglycolate) ₂ (CO) ₆] ²⁻. This was isolated as the Et ₃NH ⁺ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.
Type
Journal Article
Type of thesis
Series
Citation
Dai, Y., & Nicholson, B. K. (2012). Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl. Australian Journal of Chemistry, 65(7), 730.
Date
2012
Publisher
CSIRO Publishing