Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl

Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl

Identifier: http://hdl.handle.net/10289/6819

Date: 2012

Citation: Dai, Y., & Nicholson, B. K. (2012). Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl. Australian Journal of Chemistry, 65(7), 730.

Publisher: CSIRO Publishing

Abstract:

The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn ₂(thioglycolate) ₂ (CO) ₆] ²⁻. This was isolated as the Et ₃NH ⁺ salt and fully characterized for comparison with the previously reported thiosalicylate analogue.

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