Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii).

Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii).

Nicholson, Brian K. ; Clark, Christopher J. ; Telfer, Shane G. ; Groutso, Tania

Identifier: http://hdl.handle.net/10289/6821

Date: 2012

Citation: Nicholson, B.K., Clark, C.J., Telfer, S.G., & Groutso, T. (2011). Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii). Dalton Transactions, 41(33), 9964-9970

Publisher: The Royal Society of Chemistry.

Abstract:

The preparations and structures are described of four new polyoxostibonates, [Co(p-MeC ₆H ₄Sb) ₁₂O ₂₈{Co(H ₂O) ₃} ₄]Cl ₂₋ 6H ₂O, [Co(p-ClC ₆H ₄Sb)₁₂O ₂₈{Co(H ₂O) ₃} ₄]Cl₂₋ 22H ₂O, (PhCH ₂NMe ₃) ₂[Zn(p-ClC ₆H ₄Sb) ₁₂O ₂₈Zn ₄Cl₂•₅₄ Br ₁•₄₆]•8MeCN•H ₂O and [BaCoH ₄(p-MeC ₆H ₄Sb)O ₂₈] •5H₂O. Each of these has a framework of 12 (RSb) groups linked by 28 O atoms, with one transition metal ion in a tetrahedral site in the centre. Other metal ions are coordinated to the polyhedral faces. Three of the complexes have the ε Keggin ion geometry, while the fourth is a δ isomer.

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