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Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii).

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dc.contributor.author Nicholson, Brian K.
dc.contributor.author Clark, Christopher J.
dc.contributor.author Telfer, Shane G.
dc.contributor.author Groutso, Tania
dc.date.accessioned 2012-11-11T20:39:52Z
dc.date.available 2012-11-11T20:39:52Z
dc.date.copyright 2012
dc.date.issued 2012
dc.identifier.citation Nicholson, B.K., Clark, C.J., Telfer, S.G., & Groutso, T. (2011). Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii). Dalton Transactions, 41(33), 9964-9970 en_NZ
dc.identifier.issn 1477-9226
dc.identifier.uri http://hdl.handle.net/10289/6821
dc.description.abstract The preparations and structures are described of four new polyoxostibonates, [Co(p-MeC ₆H ₄Sb) ₁₂O ₂₈{Co(H ₂O) ₃} ₄]Cl ₂₋ 6H ₂O, [Co(p-ClC ₆H ₄Sb)₁₂O ₂₈{Co(H ₂O) ₃} ₄]Cl₂₋ 22H ₂O, (PhCH ₂NMe ₃) ₂[Zn(p-ClC ₆H ₄Sb) ₁₂O ₂₈Zn ₄Cl₂•₅₄ Br ₁•₄₆]•8MeCN•H ₂O and [BaCoH ₄(p-MeC ₆H ₄Sb)O ₂₈] •5H₂O. Each of these has a framework of 12 (RSb) groups linked by 28 O atoms, with one transition metal ion in a tetrahedral site in the centre. Other metal ions are coordinated to the polyhedral faces. Three of the complexes have the ε Keggin ion geometry, while the fourth is a δ isomer. en_NZ
dc.language.iso en
dc.publisher The Royal Society of Chemistry. en_NZ
dc.relation.ispartof Dalton Transactions
dc.subject Keggin ions en_NZ
dc.subject Tetrahedral sites en_NZ
dc.title Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii). en_NZ
dc.type Journal Article en_NZ
dc.identifier.doi 10.1039/c2dt30341h en_NZ


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