Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii).

dc.contributor.author	Nicholson, Brian K.
dc.contributor.author	Clark, Christopher J.
dc.contributor.author	Telfer, Shane G.
dc.contributor.author	Groutso, Tania
dc.date.accessioned	2012-11-11T20:39:52Z
dc.date.available	2012-11-11T20:39:52Z
dc.date.copyright	2012
dc.date.issued	2012
dc.identifier.citation	Nicholson, B.K., Clark, C.J., Telfer, S.G., & Groutso, T. (2011). Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii). Dalton Transactions, 41(33), 9964-9970	en_NZ
dc.identifier.issn	1477-9226
dc.identifier.uri	http://hdl.handle.net/10289/6821
dc.description.abstract	The preparations and structures are described of four new polyoxostibonates, [Co(p-MeC ₆H ₄Sb) ₁₂O ₂₈{Co(H ₂O) ₃} ₄]Cl ₂₋ 6H ₂O, [Co(p-ClC ₆H ₄Sb)₁₂O ₂₈{Co(H ₂O) ₃} ₄]Cl₂₋ 22H ₂O, (PhCH ₂NMe ₃) ₂[Zn(p-ClC ₆H ₄Sb) ₁₂O ₂₈Zn ₄Cl₂•₅₄ Br ₁•₄₆]•8MeCN•H ₂O and [BaCoH ₄(p-MeC ₆H ₄Sb)O ₂₈] •5H₂O. Each of these has a framework of 12 (RSb) groups linked by 28 O atoms, with one transition metal ion in a tetrahedral site in the centre. Other metal ions are coordinated to the polyhedral faces. Three of the complexes have the ε Keggin ion geometry, while the fourth is a δ isomer.	en_NZ
dc.language.iso	en
dc.publisher	The Royal Society of Chemistry.	en_NZ
dc.relation.ispartof	Dalton Transactions
dc.subject	Keggin ions	en_NZ
dc.subject	Tetrahedral sites	en_NZ
dc.title	Isopolyoxometalates derived from arylstibonic acids with "reverse-Keggin ion" structures based on [M(RSb) ₁₂O ₂₈] cores, M = Co(ii) or Zn(ii).	en_NZ
dc.type	Journal Article	en_NZ
dc.identifier.doi	10.1039/c2dt30341h	en_NZ