Nickel(II) complexes of di- and tri-substituted thiourea mono- and di-anions

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dc.contributor.authorYuen, Ho Ying
dc.contributor.authorHenderson, William
dc.contributor.authorOliver, Allen G.
dc.date.accessioned2011-02-24T03:53:16Z
dc.date.available2011-02-24T03:53:16Z
dc.date.issued2010
dc.description.abstractReaction of nickel(II) acetate, 1,2-bis(diphenylphosphino)ethane (dppe), and a di- or tri-substituted thiourea R¹NHC(S)R²R³ (R³ = H or alkyl) with trimethylamine in hot methanol gave cationic nickel(II) complexes containing N,S-chelated thiourea monoanion ligands [Ni{SC(NR²R³)NR¹}(dppe)]⁺ , which can be readily isolated as their BPh₄⁻ salts. The X-ray crystal structure of [Ni{SC(NMe₂)NPh}(dppe)]⁺BPh₄⁻ is reported.en_NZ
dc.identifier.citationYuen, H.Y., Henderson, W. & Oliver, A.G. (2010). Nickel(II) complexes of di- and tri-substituted thiourea mono- and di-anions. Inorganica Chimica Acta, available online 16 December 2010.en_NZ
dc.identifier.doi10.1016/j.ica.2010.12.011en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/5099
dc.language.isoen
dc.publisherElsevieren_NZ
dc.relation.isPartOfInorganica Chimica Actaen_NZ
dc.subjectnickel complexesen_NZ
dc.subjectthiourea complexesen_NZ
dc.subjectsulfur donor ligandsen_NZ
dc.subjectcrystal structureen_NZ
dc.titleNickel(II) complexes of di- and tri-substituted thiourea mono- and di-anionsen_NZ
dc.typeJournal Articleen_NZ
pubs.begin-page1en_NZ
pubs.elements-id35739
pubs.end-page5en_NZ
pubs.issue1en_NZ
pubs.volume368en_NZ
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