Structural studies of some compounds containing C₂ fragments attached to various metal-ligand end-groups

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dc.contributor.authorBruce, Michael I.
dc.contributor.authorGaudio, Maryka
dc.contributor.authorHall, Benjamin C.
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorPerkins, Gary J.
dc.contributor.authorSkelton, Brian W.
dc.contributor.authorWhite, Allan H.
dc.date.accessioned2011-08-07T22:00:34Z
dc.date.available2011-08-07T22:00:34Z
dc.date.issued2011
dc.description.abstractThe preparation, characterisation and single-crystal XRD molecular structure determinations of four complexes containing –CC–MLn end-groups, namely Ru{C≡CFc′(I)}(dppe)Cp (1), the vinylidene [Os(=C=CH₂)(PPh₃)₂Cp]PF₆ (2), trans-Pt(C≡CC₆H₄-4-C≡CPh){C≡CC₆H₄-4-C₂Ph[Co₂(μ-dppm)(CO)₄]}(PPh₃)₂ (3), and C₆H₄{μ₃-C₂[AuRu₃(CO)₉(PPh₃)]}₂-1,4 (4) are reported. In these compounds a range of –CC– environments is found, extending from the σ-bonded alkynyl group in 1 to examples where the C₂ unit interacts with either a proton (in vinylidene 2), by bridging a dicobalt carbonyl moiety (in 3) or the AuRu₃ cluster in 4. Changes in geometry are rationalised by considering the various bonding modes.en_NZ
dc.identifier.citationBruce, M.I., Gaudio, M., Hall, B.C., Nicholson, B.K., Perkins, G.J., …, White, A.H. (2011). Structural studies of some compounds containing C₂ fragments attached to various metal-ligand end-groups. Zeitschrift für anorganische und allgemeine Chemie, 637(9), 1207-1212.en_NZ
dc.identifier.doi10.1002/zaac.201100099en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/5552
dc.language.isoen
dc.publisherWileyen_NZ
dc.relation.isPartOfZeitschrift für anorganische und allgemeine Chemieen_NZ
dc.relation.urihttp://onlinelibrary.wiley.com/doi/10.1002/zaac.201100099/abstracten_NZ
dc.subjectC₂ ligandsen_NZ
dc.subjectmetal complexesen_NZ
dc.subjectXRD structureen_NZ
dc.subjectrutheniumen_NZ
dc.subjectosmiumen_NZ
dc.subjectplatinumen_NZ
dc.titleStructural studies of some compounds containing C₂ fragments attached to various metal-ligand end-groupsen_NZ
dc.typeJournal Articleen_NZ
pubs.begin-page1207en_NZ
pubs.elements-id36198
pubs.end-page1212en_NZ
pubs.issue9en_NZ
pubs.volume637en_NZ
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