Syntheses and Structural Studies of Several Group 8 Metal Complexes Derived from 1,3-Butadiyne

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dc.contributor.authorBruce, Michael I.
dc.contributor.authorCole, Marcus L.
dc.contributor.authorCostuas, Karine
dc.contributor.authorEllis, Benjamin G.
dc.contributor.authorKramarczuk, Kathy A.
dc.contributor.authorLapinte, Claude
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorPerkins, Gary J.
dc.contributor.authorSkelton, Brian W.
dc.contributor.authorWhite, Allan H.
dc.contributor.authorZaitseva, Natasha N.
dc.date.accessioned2013-08-30T04:38:20Z
dc.date.available2013-08-30T04:38:20Z
dc.date.copyright2013-08-27
dc.date.issued2013
dc.description.abstractAs part of an extensive investigation into the chemistry of complexes containing metal-ligand centers linked by chains of C(sp) atoms, the preparation, characterization, and single-crystal X-ray diffraction molecular structure determinations of four complexes {MLn}-C≡CC≡C-{M’L’m} [MLn = Ru(dppe)Cp*, M’L’m = Fe(dppp)Cp* (1), Ru(dppe)Cp* (2), MLn = M’L’m = Os(PPh₃)₂Cp (3)], and {Cp*(dppe)Ru}C≡CC≡C{trans-RuCl(dppe) ₂} (4), in which the alternating C(sp)–C(sp) bonds have values between 1.375 and 1.40 Å (single) and between 1.20 and 1.259 Å (triple), respectively, are described. In addition, a structure determination of Ru₃(μ-H){μ3-C2C≡C[Ru(PPh₃)₂Cp]}(CO)₉ (5) shows that the C2 fragment attached to the HRu3 cluster shows the expected lengthening [to 1.311(7) Å] and bending at the two carbon atoms [to 152.6(6) and 157.6(5)°] (resulting from back-bonding from the Ru3 cluster into the C≡C π* orbitals) compared with the essentially linear Ru–CC– moiety [C≡C 1.222(6) Å, angles at C of 178.0(5), 172.3(6)°].en_NZ
dc.identifier.citationBruce, M. I., Cole, M. L., Costuas, K., Ellis, B. G., Kramarczuk, K. A.,..., Zaitseva, N. N. (2013). Syntheses and Structural Studies of Several Group 8 Metal Complexes Derived from 1,3-Butadiyne. Zeitschrift für anorganische und allgemeine Chemie, published online 27 August 2013.en_NZ
dc.identifier.doi10.1002/zaac.201300282en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/7926
dc.language.isoenen_NZ
dc.publisherWileyen_NZ
dc.relation.isPartOfZeitschrift für anorganische und allgemeine Chemieen_NZ
dc.relation.ispartofZeitschrift für anorganische und allgemeine Chemie
dc.relation.urihttp://onlinelibrary.wiley.com/doi/10.1002/zaac.201300282/abstracten_NZ
dc.subjectDiynylen_NZ
dc.subjectstructural analysesen_NZ
dc.subjectrutheniumen_NZ
dc.subjectosmiumen_NZ
dc.titleSyntheses and Structural Studies of Several Group 8 Metal Complexes Derived from 1,3-Butadiyneen_NZ
dc.typeJournal Articleen_NZ
pubs.begin-page2216en_NZ
pubs.elements-id38917
pubs.end-page2223en_NZ
pubs.issue12-13en_NZ
pubs.volume639en_NZ
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