Electrochemistry of ferrocenylphosphines FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN), and some phosphine oxide, phosphine sulfide, phosphonium and metal complex derivatives

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dc.contributor.authorDownard, Alison J.
dc.contributor.authorGoodwin, Nicholas J.
dc.contributor.authorHenderson, William
dc.date.accessioned2009-11-24T20:39:52Z
dc.date.available2009-11-24T20:39:52Z
dc.date.issued2003
dc.description.abstractElectrochemical studies of the free ferrocenylphosphine ligands FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN) and some phosphine oxide, phosphine sulfide, phosphonium and metal derivatives are described. The free ligands exhibit complex voltammetric responses due to participation of the phosphorus lone pair in the redox reactions. Uncomplicated ferrocene-based redox chemistry is observed for PV derivatives and when the ligands are coordinated in complexes cis-PtCl₂[FcCH₂P(CH₂OH)₂], PdCl₂[FcCH₂P(CH₂OH)₂], [Au{FcCH₂P(CH₂OH)₂}₂]Cl, RuCl₂(η⁶-C₁₀H₁₄)[FcCH₂P(CH₂OH)₂] and RuCl₂(η⁶-C₁₀H₁₄)(FcCH₂PPh₂). The reaction pathways of the free ligands after one-electron oxidation have been examined in detail using voltammetry, NMR spectroscopy and electrospray mass spectrometry. Direct evidence for formation of a P---P bonded product is presented.en
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dc.identifier.citationDownard, A. J., Goodwin, N. J., Henderson, W. (2003). Electrochemistry of ferrocenylphosphines FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN), and some phosphine oxide, phosphine sulfide, phosphonium and metal complex derivatives. Journal of Organometallic Chemistry, 676(1/2), 62-72.en
dc.identifier.doi10.1016/S0022-328X(03)00309-7en
dc.identifier.urihttps://hdl.handle.net/10289/3411
dc.language.isoen
dc.publisherElsevier Science SAen_NZ
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
dc.rightsThis is an author’s accepted version of an article published in the Journal of Organometallic Chemistry. Copyright © 2003 Elsevier B.V. All rights reserved.en
dc.subjectferrocenyl groupen
dc.subjectphosphineen
dc.subjectelectrochemistryen
dc.subjectNMR spectroscopyen
dc.subjectferrocenium reactionen
dc.titleElectrochemistry of ferrocenylphosphines FcCH₂PR₂ (Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄); R=Ph, CH₂OH and CH₂CH₂CN), and some phosphine oxide, phosphine sulfide, phosphonium and metal complex derivativesen
dc.typeJournal Articleen
pubs.begin-page62en_NZ
pubs.elements-id29237
pubs.end-page72en_NZ
pubs.issue1-2en_NZ
pubs.volume676en_NZ
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