A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone

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dc.contributor.authorUjam, Oguejiofo Theophilus
dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.date.accessioned2013-08-26T05:05:45Z
dc.date.available2013-08-26T05:05:45Z
dc.date.issued2013
dc.description.abstractReaction of dinuclear platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt₂(μ-S){μ-S(CH₂)₃SO₃}•(PPh₃)₄], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.en_NZ
dc.identifier.citationUjam, O. T., Henderson, W. & Nicholson, B. K. (2013). A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone. Journal of Structural Chemisty, 54(3), 523-527.en_NZ
dc.identifier.doi10.1134/S0022476613030074en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/7893
dc.language.isoenen_NZ
dc.publisherSpringeren_NZ
dc.relation.isPartOfJournal of Structural Chemistryen_NZ
dc.relation.urihttp://link.springer.com/article/10.1134%2FS0022476613030074en_NZ
dc.subjectplatinum complexen_NZ
dc.subjectalkylation reactionen_NZ
dc.subjectzwitterionsen_NZ
dc.subjectthiolate liganden_NZ
dc.subjectX-ray crystal structureen_NZ
dc.titleA zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultoneen_NZ
dc.typeJournal Articleen_NZ
pubs.begin-page523en_NZ
pubs.elements-id38675
pubs.end-page527en_NZ
pubs.issue3en_NZ
pubs.volume54en_NZ
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