Isonitrile substitution reactions of Co₄(μ₄-SiR)₂(CO)₁₁ clusters and the structure of Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄

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dc.contributor.authorEvans, Cameronen_US
dc.contributor.authorNicholson, Brian K.en_US
dc.date.accessioned2008-03-19T05:08:11Z
dc.date.available2007-11-22en_US
dc.date.available2008-03-19T05:08:11Z
dc.date.issued2003-01-01en_US
dc.description.abstractThe substitution of carbonyl ligands by isonitriles on Co₄(μ₄-SiC₆H₄R)₂(CO)₁₁ (R=H, OMe, NMe₂) clusters has been examined. The reactions could be monitored by electrospray ionisation mass spectrometry, identifying the substituted products as either protonated [M+H]⁺ (R=NMe₂) or oxidised [M]⁺ (R=H, OMe) ions. Evidence for substitution of up to nine carbonyl ligands was found and the structure of tetra-substituted example, Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄, was determined.en_US
dc.identifier.citationEvans, C. & Nicholson, B.K. (2003). Isonitrile substitution reactions of Co₄(μ₄-SiR)₂(CO)₁₁ clusters and the structure of Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄. Journal of Organometallic Chemistry, 665(1-2), 95-100.en_US
dc.identifier.doi10.1016/S0022-328X(02)02068-5en_US
dc.identifier.urihttps://hdl.handle.net/10289/167
dc.language.isoen
dc.publisherElsevier S.A.en_NZ
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
dc.rightsThis article is published in the Journal of Organometallic Chemistry, (c) 2002 Elsevier Science B.V.en_US
dc.subjectClusteren_US
dc.subjectElectrospray mass spectrometryen_US
dc.subjectIsonitrileen_US
dc.subjectCrystal structure determinationen_US
dc.titleIsonitrile substitution reactions of Co₄(μ₄-SiR)₂(CO)₁₁ clusters and the structure of Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄en_US
dc.typeJournal Articleen_US
pubs.begin-page95en_NZ
pubs.editionJanuaryen_NZ
pubs.elements-id29321
pubs.end-page100en_NZ
pubs.issue1-2en_NZ
pubs.volume665en_NZ
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