Browsing by Author "Devoy, Sarah M."
Now showing items 1-5 of 10
-
Coordination chemistry of the [Pt₂(μ-S)₂(PPh₃)₄] metalloligand with π-hydrocarbon derivatives of d⁶ ruthenium(II), osmium(II), rhodium(III) and iridium(III)
(Elsevier S.A., 2002-08-01)The reactivity of [Pt₂(μ-S)₂(PPh₃)₄] towards [RuCl₂(η⁶-arene)]₂ (arene=C₆H₆, C₆Me₆, p-MeC₆H₄Pri=p-cymene), [OsCl₂(η⁶-p-cymene)]₂ and [MCl₂(η⁵-C₅Me₅)]₂ (M=Rh, Ir) have been probed using electrospray ionisation mass spectrometry. ... -
Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]
(Elsevier, 2010)Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt₂(μ-S)₂(PPh₃)₄]with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate ... -
Dinuclear platinum(II) complexes containing ferrocenylalkyl–thiolate and –selenolate ligands
(Elsevier, 2013)Alkylation reactions of [Pt₂(μ-S)₂(PPh₃)₄] with haloalkylferrocenes FcCH₂Cl, Fc(CH₂)₆Br and Fc(CH₂)₁₁Br [Fc = (η⁵-C₅H₅)Fe(η⁵-C₅H₄)] gave the cationic μ-thiolate complexes [Pt₂(μ-S){μ-S(CH₂)nFc}(PPh₃)₄]⁺ (n = 1, 6, 11), ... -
Dinuclear sulfide–thiolate complexes [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ as cationic metalloligands
(Elsevier, 2008)The cationic monoalkylated derivatives of the well-known metalloligand [Pt₂(μ-S)₂(PPh₃)₄], viz. [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ (R = n-Bu, CH₂Ph) are themselves able to act as metalloligands towards the Ph₃PAu⁺ and R′Hg⁺ (R′ = ... -
Dithiolate and diselenolate complexes [Pt₂(μ-ECH₂CH CHCH₂E)(PPh₃)₄]²⁺(E = S, Se): Synthesis, characterisation and mass spectrometric formation of the dichalcogenide species [Pt₂(μ-E₂)(PPh₃)₄]²⁺
(Elsevier, 2009)The reactions of [Pt₂(μ-E)₂(PPh₃)₄] (E = S, Se) with cis-1,4-dichlorobut-2-ene (cis-ClCH2CH=CHCH₂Cl) gives the dichalcogenolate complexes [Pt₂(μ-ECH₂CH=CHCH₂E)(PPh₃)₄]²⁺; an X-ray structure determination on the thiolate ...
