Browsing by Author "Evans, Cameron"
Now showing items 1-5 of 8
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Coordination isomerism in salicylhydroxamate complexes of platinum(II) and palladium(II)
(Royal Society of Chemistry, 2003-01-01)The syntheses of a range of platinum(II) and palladium(II) complexes containing salicylhydroxamate ligands are described. The ancillary ligands, together with the synthetic route, influence the coordination mode of the ... -
Electrospray mass spectrometric analysis of transition metal carbonyl clusters
(The University of Waikato, 2002)A key objective of this thesis was to develop Electrospray (Ionisation) Mass Spectrometry (ESMS) within organometallic chemistry, specifically as a technique for investigating transition metal carbonyl cluster chemistry. ... -
The formation of mixed germanium–cobalt carbonyl clusters: an electrospray mass spectrometric study, and the structure of a high-nuclearity [Ge₂Co₁₀(CO)₂₄]²⁻ anion
(2001-01-01)The reaction of [µ₄-Ge{Co₂(CO)₇}₂] with [Co(CO)₄]⁻ has been monitored by electrospray mass spectrometry to detect the cluster anions generated. Conditions giving known mixed Ge–Co carbonyl clusters were established, and a ... -
Isonitrile substitution reactions of Co₄(μ₄-SiR)₂(CO)₁₁ clusters and the structure of Co₄(μ₄-SiC₆H₄OMe)₂(CO)₇(XyNC)₄
(Elsevier S.A., 2003-01-01)The substitution of carbonyl ligands by isonitriles on Co₄(μ₄-SiC₆H₄R)₂(CO)₁₁ (R=H, OMe, NMe₂) clusters has been examined. The reactions could be monitored by electrospray ionisation mass spectrometry, identifying the ... -
Metallacyclic platinum(II) bis(sulfonamides)
(ELSEVIER SCIENCE SA, 2001-03-01)A series of metallacyclic platinum(II) bis(sulfonamido) complexes have been synthesised by reaction of cis-[PtCl₂L₂] [L_PPh₃or L₂_1,5-cyclo-octadiene (cod)] with the sulfonamides [RSO₂NHCH₂CH₂NHSO₂R, RSO₂NHCH₂CHMeNHSO₂R ...
