Browsing by Author "Ghosh, Shishir"
Now showing items 1-2 of 2
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Cleavage of Ge–S and C–H bonds in the reaction of electron-deficient [Os₃(CO)₈(μ-H)(μ₃-Ph₂PCH₂P(Ph)C₆H₄)] with Ph₃GeSPh: Generation of thiophenol derivatives [Os₃(CO)₈(μ-H)(μ-SPh)(μ-dppm)] and [Os₃(CO)₇(μ-H)(μ-SPh)(μ₃-SC₆H₄)(μ-dppm)]
(Elsevier, 2008)Heating the electron-deficient [Os₃(CO)₈(μ-H)(μ₃-Ph₂PCH₂P(Ph)C₆H₄)] (1) and Ph₃GeSPh in benzene at 80 °C led to the thiolato bridged compounds, [Os₃(CO)₈(μ-H)(μ-SPh)(μ-dppm)] (2) and [Os₃(CO)₇(μ-H)(μ-SPh)(μ₃-SC₆H₄)(μ-dppm)] ... -
Synthesis of new heterometallic complexes by tin-sulfur bond cleavage of pySSnPh₃ (pySH = pyridine-2-thiol) at triruthenium and triosmium centres
(Elsevier, 2010)The ruthenium-tin complex, [Ru₂(CO)₄(SnPh₃)₂(μ-pyS)₂] (1), the main product of the oxidative-addition of pySSnPh₃ to Ru₃(CO)₁₂ in refluxing benzene, is [Ru(CO)₂(pyS)(SnPh₃)] synthon. It reacts with PPh₃ to give ...
