Browsing by Author "Harfoot, Gwion J."
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Anomalous reaction of an aryl silane with Co₂ (CO)₂; characterisation of Me ₂NC₆H₄Si[Co(CO)₄][OCCo₃(CO)₉]₂ Harfoot, Gwion J.; Nicholson, Brian K. (Elsevier S.A., 2003-01-01)Reaction of Me₂NC₆H₄SiH₃ with Co₂(CO)₈ gave Me₂NC₆H₄Si[Co(CO)₄][OCCo₃(CO)₉]₂ which was shown to have one –Co(CO)₄ group and two –OCCo₃(CO)₉ cluster units bonded to the silicon atom.
The preparation and characterisation of monomeric and linked metal carbonyl clusters containing the closo-Si2Co4 pseudo-octahedral core Evans, Cameron; Harfoot, Gwion J.; McIndoe, J. Scott; McAdam, C. John; Mackay, Kenneth M.; Nicholson, Brian K.; Robinson, Brian H.; Van Tiel, Martin L. (Royal Society of Chemistry, 2002-01-01)PhSiH3 reacts with [Co₄(CO)₁₂] at 50 °C in hydrocarbon solvents to give [(µ₄-SiPh)₂Co₄(CO)₁₁], 2c, shown by an X-ray crystal structure determination to have a pseudo-octahedral Si₂Co₄ core. Substituted aryl-silanes behaved ...
Co-authors for Gwion J. Harfoot
Gwion J. Harfoot has 7 co-authors in Research Commons.