Now showing items 1-5 of 115

  • The arylation of [Pt₂(μ-S)₂(PPh₃)₄]

    Deadman, Benjamin Jade; Henderson, William; Nicholson, Brian K.; Petchell, Laura Eleanor; Rose, Sarah L.; Hor, T.S. Andy (Elsevier, 2009)
    Routes to the synthesis of the mixed sulfide-phenylthiolate complex [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ have been explored; reaction of [Pt₂(μ-S)₂(PPh₃)₄] with excess Ph₂IBr proceeds readily to selectively produce this complex, ...
  • Bimetallic nickel complexes with bridging dithiolato Schiff base ligands: synthesis, mass spectral characterisation and electrochemistry

    Moutloali, Richard M.; Nevondo, Funzani A.; Darkwa, James; Iwuoha, Emmanuel I.; Henderson, William (Elsevier Science SA, 2002)
    Schiff base dithiols with thiophene or phenyl linkers were prepared from condensation of the dialdehydes 2,5-(OHC)₂C₄H₂S, 1,3-(OHC)₂C₆H₄, 1,4-(OHC)₂C₆H₄ and 1,4'-(OHC)₂(C₆H₄)₂ with 4-H₂NC₆H₄(SH). The Schiff base dithiols ...
  • Bis[μ-bis(diphenylphosphino)methane-К²P:P’]bis[(saccharinato-КN)- palladium(I)] dichloromethane solvate

    Henderson, William; Nicholson, Brian K.; Chung, Dong C. (BLACKWELL MUNKSGAARD, 2002)
    The dimeric palladium(I) saccharinate complex [Pd₂(sac)₂(dppm)₂], has been characterized as its di¬chloro¬methane solvate, i.e. [Pd₂(C₇H₄NO₃S)₂(C₂₅H₂₂P₂)₂]•CH₂Cl₂. The complex features a Pd—Pd bond bridged by two dppm ...
  • Camphene-derived primary and hydroxymethyl phosphines

    Berrigan, Rebecca A.; Russell, Douglas K.; Henderson, William; Leach, Meto T.; Nicholson, Brian K.; Woodward, Gary; Harris, Christopher (ROYAL SOC CHEMISTRY, 2001-01-01)
    Thermal disproportionation of (2,2-dimethylbicyclo[2.2.1]hept-3-ylmethyl)phosphinic acid (endo-8-camphanylphosphinic acid, camPO₂H₂) yields the primary phosphine (2,2-dimethylbicyclo[2.2.1]hept-3-ylmethyl)phosphine (camPH₂). ...
  • Catalytic activity of cycloaurated complexes in the addition of 2-methylfuran to methyl vinyl ketone

    Kilpin, Kelly Joan; Jarman, Bevan P.; Henderson, William; Nicholson, Brian K. (Wiley, 2011-11)
    Cycloaurated gold(III) complexes derived from cycloaurated iminophosphorane, triphenylphosphine sulfide or selenide, or pyridylsulfonamide ligands have been assessed for their catalytic activity in the addition of 2-methylfuran ...

Showing up to 5 theses - most recently added to Research Commons first.

  • An Investigation of Beryllium Coordination Chemistry Using Electrospray Ionisation Mass Spectrometry

    Raymond, Onyekachi (The University of Waikato, 2018)
    The electrospray ionisation mass spectrometric behaviour of various complexes of beryllium have been investigated in this thesis. These beryllium complexes were prepared in situ on a small scale by preparing appropriate ...
  • Applications of Hydroxymethylphosphines

    Wyllie, Megan Jane (University of Waikato, 2015)
    Hydroxymethylphosphines are compounds containing P-CH₂-OH functional groups. They have numerous applications, of which three types were explored in this project. The cross-linking ability of tris(hydroxymethyl)phosphine ...
  • Isomerism of Complexes Containing Thiourea Dianion Ligands

    Spenceley, Jane Estelle (University of Waikato, 2014)
    This thesis reports the synthesis and characterisation of eight new platinum thiourea complexes. Thiourea dianion complexes of the type (Ph₃P)₂PtSC(=NR)NPh, R=Me, Et, Prⁿ, Prⁱ, Buⁿ and (Ph₃P)₂PtSC(=NPh)NR R=Buͭ , p-tol, ...
  • Synthesis of Platinum Complexes Containing Bidentate N,O-donor Ligands

    Sim, Sophie Anne (University of Waikato, 2014)
    The reaction of N,O-donor ligands hippuric acid and N-phenylanthranilic acid with [PtCl₂(COD)] (COD = 1,5-cyclooctadiene) in dichloromethane and in the presence of silver(I) oxide yields the complexes [Pt{OC(O)CH₂N(COPh)}(COD)] ...
  • Stabilisation effects of ferrocenylalkyl groups on hydrides of heavier main group elements

    Asamizu, Toshie (University of Waikato, 2013)
    New hydrides of heavier p-block main group elements with a ferrocenylalkyl moiety, Fc(CH₂)nEHm (Fc = (CpFeC₅H₄-); E = P, As, Si, Ge or Se; n = 1, 2, 4, 6 or 11; m = 1, 2 or 3) and FcCH₂P(R)H (R = CH₃, C₆H₁₁ or p-CH₂C₆H₄NO₂), ...

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