Browsing by Author "Leach, Meto T."

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  • Camphene-derived primary and hydroxymethyl phosphines

    Berrigan, Rebecca A.; Russell, Douglas K.; Henderson, William; Leach, Meto T.; Nicholson, Brian K.; Woodward, Gary; Harris, Christopher (ROYAL SOC CHEMISTRY, 2001-01-01)
    Thermal disproportionation of (2,2-dimethylbicyclo[2.2.1]hept-3-ylmethyl)phosphinic acid (endo-8-camphanylphosphinic acid, camPO₂H₂) yields the primary phosphine (2,2-dimethylbicyclo[2.2.1]hept-3-ylmethyl)phosphine (camPH₂). ...
  • Platinum(II) phosphonate complexes derived from endo-8-camphanylphosphonic acid

    Leach, Meto T.; Henderson, William; Wilkins, Alistair L.; Lane, Joseph R.; Fortney-Zirker, Ryland G.; Turnbull, Mark M.; Nicholson, Brian K. (Elsevier, 2011)
    The reactions of cis-[PtCl₂L₂] [L = PPh₃, PMe₂Ph or L₂ = Ph₂P(CH₂)₂PPh₂ (dppe)] with endo-8-camphanylphosphonic acid (CamPO₃H₂) and Ag₂O in refluxing dichloromethane gave platinum(II) phosphonate complexes [Pt(O₃PCam)L₂]. ...
  • Self-assembly of a columnar polymeric calcium phosphinate derived from camphene

    Henderson, William; Leach, Meto T.; Nicholson, Brian K.; Sabat, Michal (The Royal Society of Chemistry, 1995)
    (2,2-Dimethylbicyclo[2.2.1] hept-3-ylmethyl)phosphinic acid (RPO₂H₂), readily prepared from camphene and hypophosphorous acid, formed a polymeric calcium salt [{Ca(RPO₂H) ₂ (RPO₂H₂)(H₂O)}n], with both terminal and triply ...