Browsing by Author "Neo, Kian Eang"
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Dinuclear PCP pincer complexes from Lewis acidic [Pd(OTf)(PCP)] and basic [Pd(4-Spy)(PCP)] (OTf = triflate; 4-Spy = 4-pyridinethiolate; PCP = –CH(CH₂CH₂PPh₂)₂) Neo, Kian Eang; Huynh, Han Vinh; Koh, Lip Lin; Henderson, William; Hor, T.S. Andy (Royal Society of Chemistry, 2007)The Lewis acidic pincer with a labile triflate ligand, viz. [Pd(OTf)(PCP)] (PCP = –CH(CH₂CH₂PPh₂)₂) 1 was prepared from [PdCl(PCP)] with AgOTf. It reacts readily with neutral bidentate ligands [L = 4,4 -bipyridine (4,4 ...
Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II) Neo, Kian Eang; Huynh, Han Vinh; Koh, Lip Lin; Henderson, William; Hor, T.S. Andy (Elsevier, 2008)Pincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = −CH(CH₂CH₂PPh₂)₂) reacts with AgNO₃ to give [Pd(NO₃)(PCP)] (2). Similar reaction with AgBF₄ gives the aqua complex [Pd(OH₂)(PCP)][BF₄] (3) and the dinuclear complex ...
Use of cyclometallated PdCl[PPh₂CH₂CH₂CHCH₂CH₂PPh₂] as a precursor to homo and heterometallic species directed by ESMS (Electrospray Ionisation Mass Spectrometry) Neo, Kian Eang; Neo, Yew Chin; Chien, Sheau Wei; Tan, Geok Kheng; Wilkins, Alistair L.; Henderson, William (2004)The cyclometallated Pd compound PdCl[PPh₂CH₂CH₂CHCH₂CH₂PPh₂] 1, obtained from PdCl₂(Ph₂P(CH₂)₅PPh₂) in refluxing DMF (N,N-dimethylformamide), was characterized by NMR and X-ray single-crystal diffraction analysis. The ...
Co-authors for Kian Eang Neo
Kian Eang Neo has 8 co-authors in Research Commons.