Browsing by Author "Nieuwenhuyzen, Mark"
Now showing items 1-5 of 7
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1,2-Bis{(pentafluorophenyl)phenylphosphino}ethane: A Probe for Configurational Stability in Three-Legged Piano Stool Complexes
Nieuwenhuyzen, Mark; Saunders, Graham C.; Smyth, E.C.M. Sarah (American Chemical Society, 2006)The pentafluorophenyl-substituted diphosphine (C₆F₅)PhPCH₂CH₂PPh(C₆F₅) has been prepared, as a 1:1.7 mixture of rac (1a) and meso (1b) isomers, in four steps from dppe. The reaction between [Cp*RhCl(μ-Cl)]2 and 1 in the ... -
Complexes of η⁵, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η⁵-pentamethylcyclopentadienyl in a rhodium complex
Marr, Andrew C.; Nieuwenhuyzen, Mark; Pollock, Ciara L.; Saunders, Graham C. (Elsevier, 2006)The reaction between [{(η⁵-C₅Me₅)RhCl(μ-Cl)}₂] and (C₆F₅)₂PCH₂P(C₆F₅)₂ in refluxing benzene yields the singly linked complex [{(η⁵,κP-C₅Me₄ CH₂C₆F₄-2-P(C₆F₅)CH₂P(C₆F₅)₂)}RhCl₂] in which only one phosphorus atom is coordinated ... -
Crystal structure of (η⁵ pentamethylcyclopentadienyl){bis(pentafluorophenyl)×thiomethylphenyl phosphine-κ₂ S,P)chloro-iridium(III) tetrafluoroborate
Bellabarba, R. M.; Nieuwenhuyzen, Mark; Saunders, Graham C. (Springer, 2013)The salt (η⁵-pentamethylcyclopentadienyl){bis(pentafluorophenyl)thiomethylphenylphosphine-κ₂ S,P)chloroiridium(III) tetrafluoroborate, [(η⁵-C₅Me₅)IrCl{κ₂ S,P-(C₆F₅)₂PC₆H₄SMe-2}]BF₄, crystallizes as a conglomerate in the ... -
Crystal structure of (η⁵-pentamethylcyclo-pentadienyl)(methyldiphenylphosphite-P)dichlororhodium(III)
Nieuwenhuyzen, Mark; Saunders, Graham C. (Springer-Verlag, 2013)The molecule (η⁵-pentamethylcyclopentadienyl)(methyldiphenylphosphinite-P)dichlororhodium(III), [(η⁵-C₅Me₅)RhCl₂(PPh₂OMe)], crystallizes in the monoclinic crystal system in space group P2₁/c with unit cell parameters a = ... -
Intramolecular dehydrofluorinative coupling of η⁶-arene and fluoroarylphosphine ligands in ruthenium complexes
McGibbon, Angela; Nieuwenhuyzen, Mark; Saunders, Graham C. (Elsevier, 2011)NMR studies of reactions between a series of arene ruthenium(II) fluoroarylphosphine complexes and Proton Sponge have revealed the necessary conditions for intramolecular dehydrofluorinative ligand coupling. The complex ...
Co-authors for Mark Nieuwenhuyzen
Mark Nieuwenhuyzen has 9 co-authors in Research Commons.