Browsing by Author "Robinson, Ward T."
Now showing items 1-3 of 3
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(Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry
(Springer, 2008)There are two molecules in the asymmetric unit of the P2₁/c unit cell of ClCH₂Mn(CO)₅, the first halomethyl complex of manganese to be structurally determined. The molecules are crystallographically independent, despite ... -
Preparation and the crystal and molecular structure of [Net₄][Ge{Co₂(CO)₇}{Co₂(CO)₆[HgCo(CO)₄]}]: an anion containing a mercury-bridged cobalt–cobalt bond
(1981)The title compound has been isolated from the reaction of Gel4 with Na[Co(CO)₄] in the presence of Hg and has been characterised by X-ray analysis. Crystals are triclinic, a= 12.065(1), b= 17.334(2), c= 9.222(1)Å, α= ... -
Transition-metal carbonyl derivatives of the germanes. Part 13. Preparation, spectroscopic properties, and the crystal and molecular structure of bis[µ-carbonyl-bis(tricarbonylcobaltio)(Co–Co)]germanium (4Co–Ge), [Ge{Co₂(CO)₇}₂]; a new type of group 4–tetracobalt species
(1981)Reaction between Gel₄ and [Co(CO)₄]⁻ or between GeH₄ and [Co₂(CO)₈] gives [Ge{Co₂(CO)₇}₂](1). The crystal and molecular structure of (1) has been obtained by X-ray methods. Crystals are triclinic, with a= 10.396(2), b= ...
