Browsing by Author "Rose, Sarah L."

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  • The arylation of [Pt₂(μ-S)₂(PPh₃)₄]

    Deadman, Benjamin Jade; Henderson, William; Nicholson, Brian K.; Petchell, Laura Eleanor; Rose, Sarah L.; Hor, T.S. Andy (Elsevier, 2009)
    Routes to the synthesis of the mixed sulfide-phenylthiolate complex [Pt₂(μ-S)(μ -SPh)(PPh₃)₄]⁺ have been explored; reaction of [Pt₂(μ-S)₂(PPh₃)₄] with excess Ph₂IBr proceeds readily to selectively produce this complex, ...
  • Thallium(III) complexes of the metalloligands [Pt₂(μ-S)₂(PPh₃)₄] and [Pt₂(μ-Se)₂(PPh₃)₄]

    Rose, Sarah L.; Henderson, William; Nicholson, Brian K.; Hor, T.S. Andy (Elsevier B.V., 2009)
    Reactions of [Pt₂(μ-S)₂(PPh₃)₄] with the diarylthallium(III) bromides Ar₂TlBr [Ar = Ph and p-ClC₆H₄] in methanol gave good yields of the thallium(III) adducts [Pt₂(μ-S)₂(PPh₃)4TlAr₂]⁺, isolated as their BPh₄⁻ salts. The ...