Browsing by Author "Wright, Cody Elvin"
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Arylstibonic acids [H₈(RSb)₁₂O₂₈]; precursors to organometallic isopolyoxostibonates [Na₂H₉(RSb)₁₂O₃₀]-, (R = aryl).
(Royal Society of Chemistry, 2009)Electrospray ionisation mass spectrometry shows that arylstibonic acids, RSbO₃H₂, give rise to oxo-bridged clusters derived from [H₈(RSb)₁₂O₂₈] which act as inorganic crown ligands towards Na+ cations; structure determination ... -
The Composition of Arylstibonic Acids
(University of Waikato, 2010)This thesis describes a detailed ESI-MS investigation into the arylstibonic acids, organo-antimony-containing compounds that are currently of interest as anticancer reagents. Four arylstibonic acids, of nominal formula ... -
Isopolyoxometalates of Antimony: Arylstibonic Acids [H₈ (RSb)₁₂O₂₈] and Derived Dodecanuclear Polyoxostibonates [M₂H10−x(RSb)₁₂O₃₀]x−, M = Na or K
(American Chemical Society, 2010)Electrospray ionization mass spectrometry shows arylstibonic acids, p-XC₆H₄SbO₃H₂ (X = methyl, nitro, or chloro), and 1-naphthylstibonic acid exist in MeCN as dodecanuclear aggregates [H₈(RSb)₁₂O₂₈]. With KOH or NaOH these ... -
New Sb₁₂ and Sb₁₄ Polyoxometalate Frameworks Derived from Arylstibonic Acids: [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻ and [BaH₁₀(p-MeC₆H₄Sb)₁₄O₃₄]
(American Chemistry Society, 2011)The lithium salt of p-tolylstibonic acid contains the anion [LiH₃(p-MeC₆H₄Sb)₁₂O₂₈]⁴⁻, in which the Li⁺ is fully enclosed within an {Sb₁₂O₂₈} cage with γ Keggin ion geometry; the idealized overall formula is Li₅[LiH₃(p-M ...
