Browsing by Subject "Intramolecular dehydrofluorinative carbon–carbon coupling"
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The effect of trifluoromethyl groups in the para positions of a perfluoroaryl phosphine: A comparison of the structures of [{η⁵,κP-C₅Me₄CH₂C₆F₃X-5-P(C₆F₄X-4)-2-CH₂P(C₆F₄X-4)₂}RhCl₂], X = F and CF₃
(Elsevier, 2010)The complex [{η⁵,κP-C₅Me₄CH₂C₆F₃CF₃-5-P(C₆F₄CF₃-4)-2-CH₂P(C₆F₄CF₃-4)₂}RhCl₂] (2) was formed by dehydrofluorinative carbon–carbon coupling in the reaction between bis{bis(4-trifluoromethyltetrafluorophenyl)phosphino}methane ...