Browsing by Subject "Tricyanovinylalkynyl–metal"

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  • Tricyanovinylalkynyl–metal complexes: synthesis and some reactions

    Bruce, Michael I.; Burgun, Alexandre; Kramarczuk, Kathy A.; Nicholson, Brian K.; Parker, Christian R.; Skelton, Brian W.; White, Allan H.; Zaitseva, Natasha N. (Royal Society of Chemistry, 2008)
    Reactions of Group 8 metal ethynyls with tetracyanoethene afford tricyanovinylethynyl–metal derivatives, M{C≡CC(CN)=C(CN)2}(PP)Cp’ [2; M = Ru, Os; PP = (PPh3)2, dppe;Cp’=Cp,Cp*; not all combinations]; a similar reaction ...