Browsing by Subject "isotope effect"

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Uncovering the relationship between the change in heat capacity for enzyme catalysis and vibrational frequency through isotope effect studies

Jones, Hannah B.L.; Crean, Rory M.; Matthews, Christopher; Troya, Anna B.; Danson, Michael J.; Bull, Steven D.; Arcus, Vickery L.; van der Kamp, Marc W.; Pudney, Christopher R. (American Chemical Society, 2018)

Understanding how enzyme catalysis varies with temperature is key to understanding catalysis itself and, ultimately, how to tune temperature optima. Temperature dependence studies inform on the change in heat capacity ...