Browsing by Subject "sulfide ligands"
Now showing items 1-5 of 5
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Coordination chemistry of the [Pt₂(μ-S)₂(PPh₃)₄] metalloligand with π-hydrocarbon derivatives of d⁶ ruthenium(II), osmium(II), rhodium(III) and iridium(III)
(Elsevier S.A., 2002-08-01)The reactivity of [Pt₂(μ-S)₂(PPh₃)₄] towards [RuCl₂(η⁶-arene)]₂ (arene=C₆H₆, C₆Me₆, p-MeC₆H₄Pri=p-cymene), [OsCl₂(η⁶-p-cymene)]₂ and [MCl₂(η⁵-C₅Me₅)]₂ (M=Rh, Ir) have been probed using electrospray ionisation mass spectrometry. ... -
Coordination chemistry of the metalloligand [Pt₂(μ-S)₂(PPh₃)₄] with nickel(II) complexes – an electrospray mass spectrometry directed synthetic study
(Elsevier B.V., 2004)The reactivity of [Pt₂(μ-S)₂(PPh₃)₄] towards a range of nickel(II) complexes has been probed using electrospray ionisation mass spectrometry coupled with synthesis and characterisation in selected systems. Reaction of ... -
Further studies on the chemistry of molybdenyl adducts of [Pt₂(μ-S)₂(PPh₃)₄]: Hydrolysis, condensation and ligand exchange processes
(Elsevier, 2011)Reaction of [Pt₂(μ-S)₂(PPh₃)₄] with [MoO₂(acac)₂] in methanol gives the known five-coordinate Mo(VI) adduct [Pt₂(μ-S)₂(PPh₃)₄MoO₂(OMe)]⁺ isolated as its PF₆⁻, BPh₄⁻ and [Mo₈O₂₆]₄⁻ salts; the latter was structurally ... -
Further studies on the coordination chemistry of [Pt₂(μ-S)₂(PPh₃)₄] towards indium(III) substrates
(Elsevier, 2011)The reactivity of the metalloligand [Pt₂(μ-S)₂(PPh₃)₄] towards a variety of indium(III) substrates has been explored. Reaction with excess In(NO₃)₃ and halide (KBr or NaI) gave the four-coordinate adducts [Pt₂(μ-S)₂(PPh₃ ... -
Thallium(III) complexes of the metalloligands [Pt₂(μ-S)₂(PPh₃)₄] and [Pt₂(μ-Se)₂(PPh₃)₄]
(Elsevier B.V., 2009)Reactions of [Pt₂(μ-S)₂(PPh₃)₄] with the diarylthallium(III) bromides Ar₂TlBr [Ar = Ph and p-ClC₆H₄] in methanol gave good yields of the thallium(III) adducts [Pt₂(μ-S)₂(PPh₃)4TlAr₂]⁺, isolated as their BPh₄⁻ salts. The ...
