Browsing by Subject "sulfur atoms"
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Synthesis and structure of a dimeric, anionic thioglycolate derivative of manganese carbonyl
(CSIRO Publishing, 2012)The thioglycolate anion reacts with BrMn(CO)5 to form a dimeric complex with bridging sulfur atoms of formula [Mn ₂(thioglycolate) ₂ (CO) ₆] ²⁻. This was isolated as the Et ₃NH ⁺ salt and fully characterized for comparison ...