Browsing by Subject "x-ray crystal structures"

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Orthomercurated and cycloaurated derivatives of the iminophosphorane Ph3P NPh

Brown, Samuel D.J.; Henderson, William; Kilpin, Kelly Joan; Nicholson, Brian K. (Elsevier BV, 2007-03-01)

Ortho-lithiation of Ph3P NPh followed by reaction with HgCl2 gave good yields of [Hg{C6H4(PPh2 NPh)-2}Cl], 3, which was characterised spectroscopically and by an X-ray crystal structure determination. This is an isomer of ...
Synthesis and reactivity of gold(III) complexes containing cycloaurated iminophosphorane ligands

Kilpin, Kelly Joan; Henderson, William; Nicholson, Brian K. (Elsevier, 2009)

Transmetallation reactions of ortho-mercurated iminophosphoranes (2-ClHgC₆H₄)Ph₂P NR with [AuCl₄]⁻ gives new cycloaurated iminophosphorane complexes of gold(III) (2-Cl₂AuC₆H₄)Ph₂P NR [R = (R,S)- or (S)-CHMePh, p-C₆H₄F, ...