Browsing by Subject "cyclometallation"

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Reactions of Some Cyclomanganated Compounds with C-Nitroso Compounds, Allenes, and Ketenimines

Revell, John Bernard (The University of Waikato, 2008)

eta2-(5-Methoxy-2-acetylphenyl)tetracarbonylmanganese (30) was reacted with 2-methyl-2-nitrosopropane (31) to form 2-acetyl-5-methoxy-N-(tert-butyl)aniline(43) in low yield. Attempts to improve the yield by varying the ...
Synthesis and alkyne-coupling chemistry of cyclomanganated 1- and 3-acetylindoles, 3-formylindole and analogues

Depree, Gary J.; Main, Lyndsay; Nicholson, Brian K.; Robinson, Nicholas P.; Jameson, Geoffrey B. (Elsevier S.A, 2006-02-01)

The syntheses are reported of new cyclomanganated indole derivatives (1-acetyl-κO-indolyl-κC2)dicarbonylbis(trimethylphosphite)manganese (2), (1-methyl-3-acetyl-κO-indolyl-κC2)tetracarbonylmanganese (4), (3-formyl-κO-ind ...