Browsing by Subject "pySSnPh₃"

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Synthesis of new heterometallic complexes by tin-sulfur bond cleavage of pySSnPh₃ (pySH = pyridine-2-thiol) at triruthenium and triosmium centres

Raha, Arun K.; Ghosh, Shishir; Hossain, Iqbal; Kabir, Shariff E.; Nicholson, Brian K.; Hogarth, Graeme; Salassa, Luca (Elsevier, 2010)

The ruthenium-tin complex, [Ru₂(CO)₄(SnPh₃)₂(μ-pyS)₂] (1), the main product of the oxidative-addition of pySSnPh₃ to Ru₃(CO)₁₂ in refluxing benzene, is [Ru(CO)₂(pyS)(SnPh₃)] synthon. It reacts with PPh₃ to give ...