Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]
| dc.contributor.author | Ujam, Oguejiofo Theophilus | |
| dc.contributor.author | Devoy, Sarah M. | |
| dc.contributor.author | Henderson, William | |
| dc.contributor.author | Nicholson, Brian K. | |
| dc.contributor.author | Hor, T.S. Andy | |
| dc.date.accessioned | 2010-07-30T03:23:28Z | |
| dc.date.available | 2010-07-30T03:23:28Z | |
| dc.date.issued | 2010 | |
| dc.description.abstract | Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt₂(μ-S)₂(PPh₃)₄]with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt₂(μ-S)(μ-SR)(PPh₃)₄]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. | en_NZ |
| dc.format.mimetype | application/pdf | |
| dc.identifier.citation | Ujam, O.T., Devoy, S.M., Henderson, W., Nicholson, B.K. & Hor, T.S.A. (2010). Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄]. Inorganica Chimica Acta, Available online 14 July 2010. | en_NZ |
| dc.identifier.doi | 10.1016/j.ica.2010.07.011 | en_NZ |
| dc.identifier.uri | https://hdl.handle.net/10289/4218 | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | en_NZ |
| dc.relation.isPartOf | Inorganica Chimica Acta | en_NZ |
| dc.rights | This is an author’s accepted version of an article published in the journal: Inorganica Chimica Acta. © 2010 Elsevier. | en_NZ |
| dc.subject | platinum complexes | en_NZ |
| dc.subject | sulfido complexes | en_NZ |
| dc.subject | thiolate complexes | en_NZ |
| dc.subject | crystal structure | en_NZ |
| dc.subject | alkylation reactions health | en_NZ |
| dc.title | Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt₂(μ-S)₂(PPh₃)₄] | en_NZ |
| dc.type | Journal Article | en_NZ |
| dspace.entity.type | Publication | |
| pubs.begin-page | 3558 | en_NZ |
| pubs.end-page | 3568 | en_NZ |
| pubs.issue | 13 | en_NZ |
| pubs.volume | 363 | en_NZ |