Tricyanovinylalkynyl–metal complexes: synthesis and some reactions

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dc.contributor.authorBruce, Michael I.
dc.contributor.authorBurgun, Alexandre
dc.contributor.authorKramarczuk, Kathy A.
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorParker, Christian R.
dc.contributor.authorSkelton, Brian W.
dc.contributor.authorWhite, Allan H.
dc.contributor.authorZaitseva, Natasha N.
dc.date.accessioned2009-08-03T22:12:29Z
dc.date.available2009-08-03T22:12:29Z
dc.date.issued2008
dc.description.abstractReactions of Group 8 metal ethynyls with tetracyanoethene afford tricyanovinylethynyl–metal derivatives, M{C≡CC(CN)=C(CN)2}(PP)Cp’ [2; M = Ru, Os; PP = (PPh3)2, dppe;Cp’=Cp,Cp*; not all combinations]; a similar reaction occurs with the vinylidene RuCl(=C=CHPh)(PPh3)Cp. Further replacement of a CNgroup in 2 occurs with nucleophiles, while homo- and hetero-metallic derivatives are obtained by coordination of one of the remaining CN groups to other metal–ligand fragments.en
dc.identifier.citationBruce, M. I., Burgun, A., Kramarczuk, K. A., Nicholson, B. K., Parker, C. R., Skelton, B. W., White, A. H. & Zaitseva, N. N. (2008). Tricyanovinylalkynyl–metal complexes: synthesis and some reactions. Dalton Transactions, 7(1), 33-36.en
dc.identifier.doi10.1039/b810720cen
dc.identifier.urihttps://hdl.handle.net/10289/2732
dc.language.isoen
dc.publisherRoyal Society of Chemistryen_NZ
dc.relation.isPartOfDalton Transactionsen_NZ
dc.relation.urihttp://www.rsc.org/ej/DT/2009/b810720c.pdfen
dc.subjectchemistryen
dc.subjectTricyanovinylalkynyl–metalen
dc.titleTricyanovinylalkynyl–metal complexes: synthesis and some reactionsen
dc.typeJournal Articleen
dspace.entity.typePublication
pubs.begin-page33en_NZ
pubs.end-page36en_NZ
pubs.issue1en_NZ
pubs.volume7en_NZ

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