Base-Free Dynamic Kinetic Resolution of Secondary Alcohols Using “Piano-Stool” Complexes of N-Heterocyclic Carbenes

dc.contributor.author	Marr, Andrew C.
dc.contributor.author	Pollock, Ciara L.
dc.contributor.author	Saunders, Graham C.
dc.date.accessioned	2009-05-18T02:03:52Z
dc.date.available	2009-05-18T02:03:52Z
dc.date.issued	2007
dc.description.abstract	“Piano-stool” complexes of rhodium and iridium activated by fluorinated and non-fluorinated N-heterocyclic carbene (NHC) ligands were shown to be catalysts for racemization in the one-pot chemoenzymic dynamic kinetic resolution (DKR) of secondary alcohols. Excellent conversions and good enantioselectivities were observed for alkyl aryl and dialkyl secondary alcohols.	en
dc.identifier.citation	Marr, A. C., Pollock, C. L. & Saunders, G. C., (2007). Base-Free dynamic kinetic resolution of secondary alcohols using “Piano-stool” complexes of N-heterocyclic carbenes. Organometallics, 26(10), 2659-2671.	en
dc.identifier.doi	10.1021/om700462c	en
dc.identifier.uri	https://hdl.handle.net/10289/2168
dc.language.iso	en
dc.publisher	American Chemical Society	en_NZ
dc.relation.isPartOf	Organometallics	en_NZ
dc.relation.uri	http://pubs.acs.org/doi/abs/10.1021/om700462c	en
dc.subject	chemistry	en
dc.subject	Piano-stool complexes	en
dc.title	Base-Free Dynamic Kinetic Resolution of Secondary Alcohols Using “Piano-Stool” Complexes of N-Heterocyclic Carbenes	en
dc.type	Journal Article	en
dspace.entity.type	Publication
pubs.begin-page	3283	en_NZ
pubs.end-page	3285	en_NZ
pubs.issue	14	en_NZ
pubs.volume	26	en_NZ

Files

Now showing 1 - 1 of 1