A six-coordinate aryl-germanium complex formed by the Kläui ligand

Davidson, Kelly A.; Kilpin, Kelly Joan; Lloyd, Nicholas C.; Nicholson, Brian K.

doi:10.1016/j.jorganchem.2007.01.009

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Davidson, K.A., Kilpin, K.J., Lloyd, N.J. & Nicholson, B.K. (2007) A six-coordinate aryl-germanium complex formed by the Klui ligand. Journal of Organometallic Chemistry, 692, 1871-1874.

Permanent Research Commons link: https://hdl.handle.net/10289/133

Abstract

PhGeCl₃ reacts with Na{[OP(OEt)₂]₃CoCp} to give the six-coordinate complex PhCl₂Ge{[OP(OEt)₂]₃CoCp}, characterised spectroscopically and by an X-ray crystal structure determination which showed a firmly-attached tridentate ligand [Ge–O 1.973(2) Å].

Date

2007-04-01

Type

Journal Article

Publisher

Elsevier

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Science and Engineering Papers [3124]