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dc.contributor.authorBuchner, Magnus R.en_NZ
dc.contributor.authorMüller, Matthiasen_NZ
dc.contributor.authorRaymond, Onyekachien_NZ
dc.contributor.authorSeverinsen, Rebecca J.en_NZ
dc.contributor.authorNixon, David J.en_NZ
dc.contributor.authorHenderson, Williamen_NZ
dc.contributor.authorBrothers, Penelope J.en_NZ
dc.contributor.authorRowlands, Gareth J.en_NZ
dc.contributor.authorPlieger, Paul G.en_NZ
dc.date.accessioned2020-02-25T23:46:40Z
dc.date.available2019-08-23en_NZ
dc.date.available2020-02-25T23:46:40Z
dc.date.issued2019en_NZ
dc.identifier.citationBuchner, M. R., Müller, M., Raymond, O., Severinsen, R. J., Nixon, D. J., Henderson, W., … Plieger, P. G. (2019). Synthesis of a boronic acid anhydride based ligand and its application in beryllium coordination. European Journal of Inorganic Chemistry, 2019(34), 3863–3868. https://doi.org/10.1002/ejic.201900772en
dc.identifier.issn1434-1948en_NZ
dc.identifier.urihttps://hdl.handle.net/10289/13463
dc.description.abstractThe synthesis of a boronic acid anhydride‐based ligand containing one three‐ and one four‐coordinated boron atom is presented. This ligand was successfully employed as a tridentate κ¹N,κ²O‐ligand in the coordination of beryllium chloride and both the ligand and the resulting complex have been structurally characterized. While the boron‐element separations are within the typical range of related homo‐nuclear compounds, the corresponding beryllium‐element distances are rather long, suggesting unexpectedly high electron density at the beryllium center. Incorporation of a beryllium atom in a six‐membered ring causes no more distortion than the corresponding boron atom, suggesting that analogous ligand systems could be used in boron and beryllium coordination chemistry. The generated hetero‐tri‐nuclear complex enables the direct comparison of bond lengths and angles at beryllium and boron atoms in similar coordination environments and can act as a monomolecular model for beryllium borates.
dc.format.mimetypeapplication/pdf
dc.language.isoenen_NZ
dc.publisherWiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_NZ
dc.rights© 2019 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
dc.subjectScience & Technologyen_NZ
dc.subjectPhysical Sciencesen_NZ
dc.subjectChemistry, Inorganic & Nuclearen_NZ
dc.subjectChemistryen_NZ
dc.subjectBerylliumen_NZ
dc.subjectBoronen_NZ
dc.subjectCoordination modesen_NZ
dc.subjectMain group chemistryen_NZ
dc.subjectStructure elucidationen_NZ
dc.subjectLIGHT-EMITTING-DIODESen_NZ
dc.subjectDEEP-BLUE PHOTOLUMINESCENCEen_NZ
dc.subjectNONLINEAR-OPTICAL CRYSTALen_NZ
dc.subjectCOMPLEXESen_NZ
dc.subjectBORATEen_NZ
dc.subjectGENERATIONen_NZ
dc.subjectBINDINGen_NZ
dc.subjectPHASEen_NZ
dc.subjectOLEDSen_NZ
dc.subjectIRen_NZ
dc.titleSynthesis of a boronic acid anhydride based ligand and its application in beryllium coordinationen_NZ
dc.typeJournal Article
dc.identifier.doi10.1002/ejic.201900772en_NZ
dc.relation.isPartOfEuropean Journal of Inorganic Chemistryen_NZ
pubs.begin-page3863
pubs.elements-id240679
pubs.end-page3868
pubs.issue34en_NZ
pubs.publication-statusPublisheden_NZ
pubs.volume2019en_NZ
dc.identifier.eissn1099-0682en_NZ


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