A manganese carbonyl complex derived from the P,N-bonding ligand (2-aminophenyl)diphenylphosphine
Citation
Export citationFester, V.D., Houghton, P.J., Main, L. & Nicholson, B.K. (2007). A manganese carbonyl complex derived from the P,N-bonding ligand (2-aminophenyl)diphenylphosphine. Polyhedron, 26, 430-433.
Permanent Research Commons link: https://hdl.handle.net/10289/165
Abstract
Thermal reaction of [H₃Mn₃(CO)₁₂] with Ph₂PC₆H₄NH₂-2 gives good yields of [Mn₂(CO)₆(PPh₂C₆H₄NH)₂], an X-ray single crystal structure determination of which reveals a P,N-chelating ligand with each of the NH groups, formed by deprotonation of the amine groups, bridging the two metal atoms.
Date
2007-01-01Type
Publisher
Elsevier BV
Rights
This is an authors version of an article published in the journal, Polyhedron, (c) 2006 Elsevier Ltd