Show simple item record  

dc.contributor.authorMace, Wadeen_US
dc.contributor.authorMain, Lyndsayen_US
dc.contributor.authorNicholson, Brian K.en_US
dc.contributor.authorvan de Pas, Daniel J.en_US
dc.date.accessioned2008-03-19T05:08:10Z
dc.date.available2007-08-30en_US
dc.date.available2008-03-19T05:08:10Z
dc.date.issued2004-08-01en_US
dc.identifier.citationMace, W.J., Main, L., Nicholson, B.K. & van de Pas, D.J. (2004). Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules. Journal of Organometallic Chemistry, 689, 2523-2530.en_US
dc.identifier.urihttps://hdl.handle.net/10289/174
dc.description.abstractReaction of PhCH₂Mn(CO)₅ with l,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which were η⁴-coordinated to a Mn(CO)₃ group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed by cyclisation. Other unsaturated reagents (PhC≡CH, CH2=CHCOOMe, PhNCO) gave products arising from insertion of these, including a structurally characterised tri-aryl-η⁵-azacyclohexadienyl-Mn(CO)₃ complex from the reaction with the alkyne. PhCH₂Mn(CO)₅ reacts with l,4-di-aryl-1-aza-1,3-butadienes in the presence of unsaturated substrates to give products based on a cyclomanganated intermediate.en_US
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherElsevier SAen_NZ
dc.relation.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504090/description#descriptionen_US
dc.rightsThis is an authors version of an article published in the, Journal of Organometallic Chemistry, (c) 2004 Elsevier Science B.V.en_US
dc.subjectazabutadienesen_US
dc.subjectmanganeseen_US
dc.subjectcarbonyl phenylacetyleneen_US
dc.titleManganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated moleculesen_US
dc.typeJournal Articleen_US
dc.identifier.doi10.1016/j.jorganchem.2004.04.042en_US
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page2523en_NZ
pubs.elements-id30275
pubs.end-page2530en_NZ
pubs.issue15en_NZ
pubs.volume689en_NZ


Files in this item

This item appears in the following Collection(s)

Show simple item record