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      Base-Free Dynamic Kinetic Resolution of Secondary Alcohols Using “Piano-Stool” Complexes of N-Heterocyclic Carbenes

      Marr, Andrew C.; Pollock, Ciara L.; Saunders, Graham C.
      DOI
       10.1021/om700462c
      Link
       pubs.acs.org
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      Citation
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      Marr, A. C., Pollock, C. L. & Saunders, G. C., (2007). Base-Free dynamic kinetic resolution of secondary alcohols using “Piano-stool” complexes of N-heterocyclic carbenes. Organometallics, 26(10), 2659-2671.
      Permanent Research Commons link: https://hdl.handle.net/10289/2168
      Abstract
      “Piano-stool” complexes of rhodium and iridium activated by fluorinated and non-fluorinated N-heterocyclic carbene (NHC) ligands were shown to be catalysts for racemization in the one-pot chemoenzymic dynamic kinetic resolution (DKR) of secondary alcohols. Excellent conversions and good enantioselectivities were observed for alkyl aryl and dialkyl secondary alcohols.
      Date
      2007
      Type
      Journal Article
      Publisher
      American Chemical Society
      Collections
      • Science and Engineering Papers [3122]
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