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dc.contributor.authorRevell, John Bernarden_NZ
dc.date.accessioned2008-02-15T11:24:14Z
dc.date.available2008-08-01T11:44:01Z
dc.date.issued2008en_NZ
dc.identifier.citationRevell, J. B. (2008). Reactions of Some Cyclomanganated Compounds with C-Nitroso Compounds, Allenes, and Ketenimines (Thesis, Master of Science (MSc)). The University of Waikato, Hamilton, New Zealand. Retrieved from https://hdl.handle.net/10289/2275en
dc.identifier.urihttps://hdl.handle.net/10289/2275
dc.description.abstracteta2-(5-Methoxy-2-acetylphenyl)tetracarbonylmanganese (30) was reacted with 2-methyl-2-nitrosopropane (31) to form 2-acetyl-5-methoxy-N-(tert-butyl)aniline(43) in low yield. Attempts to improve the yield by varying the solvent were unsuccessful. Substrate 30 was reacted with nitrosodurene and orthomanganated triphenylphosphine sulfide was reacted with 2-methyl-2-nitrosopropane (31), however no new compounds were characterised in either case. Acetylallene (55) was reacted with 30. Electrospray ionisation-mass spectrometry(ESI-MS) provided evidence for the insertion of one and two molecules of 55 into the Mn-C bond of 30 to form the products tentatively identified as 56 and 57. The reaction of orthomanganated triphenylphosphine sulfide with acetylallene was attempted but no new compounds were characterised. In order to extend the study to ketenimines, the synthesis of the diphenylketene N-(p-tolyl)imine was attempted by the dehydration of N-(p-tolyl)diphenylacetamide under a variety of conditions, but it was not isolated in useful quantities. A single preliminary study of the reaction of diphenylketene N-(p-tolyl)imine with 30 gave an intense green solution, but no products were isolated.en_NZ
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherThe University of Waikatoen_NZ
dc.rightsAll items in Research Commons are provided for private study and research purposes and are protected by copyright with all rights reserved unless otherwise indicated.
dc.subjectcyclomanganateden_NZ
dc.subjectketeniminesen_NZ
dc.subjectallenesen_NZ
dc.subjectC-nitrosoen_NZ
dc.subjectcyclometallationen_NZ
dc.subjectorthomanganateden_NZ
dc.subjectorganometallicen_NZ
dc.titleReactions of Some Cyclomanganated Compounds with C-Nitroso Compounds, Allenes, and Keteniminesen_NZ
dc.typeThesisen_NZ
thesis.degree.disciplineChemistryen_NZ
thesis.degree.grantorUniversity of Waikatoen_NZ
thesis.degree.levelMasters
thesis.degree.nameMaster of Science (MSc)en_NZ
uow.date.accession2008-02-15T11:24:14Zen_NZ
uow.date.available2008-08-01T11:44:01Zen_NZ
uow.identifier.adthttp://adt.waikato.ac.nz/public/adt-uow20080215.112414en_NZ
uow.date.migrated2009-06-09T23:33:45Zen_NZ
pubs.place-of-publicationHamilton, New Zealanden_NZ


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