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      (p -Cymene)thioglycollatoruthenium(II) dimer; a complex with an ambi-basic S,O-donor ligand

      Henderson, William; Kilpin, Tracey D.; Nicholson, Brian K.
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      Nicholson p-Cymene.pdf
      280.8Kb
      DOI
       10.1007/s11224-007-9272-9
      Link
       www.springerlink.com
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      Henderson, W., Kilpin, T. D. & Nicholson, B. K. (2007). (p -Cymene)thioglycollatoruthenium(II) dimer; a complex with an ambi-basic S,O-donor ligand. Structural Chemistry, 19(2), 199-202.
      Permanent Research Commons link: https://hdl.handle.net/10289/2681
      Abstract
      The title compound was prepared from the (p-cymene)ruthenium chloride dimer and thioglycollic acid. The structure is a centrosymmetric dimer bridged by the soft-base S atoms, with the hard-base O atoms of the carboxylate group chelating to form a five-membered twisted-ring. The coordination of the ruthenium atoms is completed by a η6-p-cymene ligand, giving an 18-electron count. The Ru–S bonds are essentially equal at 2.396(1) Å.
      Date
      2007
      Type
      Journal Article
      Publisher
      Springer
      Rights
      This is the author's accepted version of an article published in the journal: Structural Chemistry. The original publication is available at www.springerlink.com.
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      • Science and Engineering Papers [3011]
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