(p -Cymene)thioglycollatoruthenium(II) dimer; a complex with an ambi-basic S,O-donor ligand
Henderson, W., Kilpin, T. D. & Nicholson, B. K. (2007). (p -Cymene)thioglycollatoruthenium(II) dimer; a complex with an ambi-basic S,O-donor ligand. Structural Chemistry, 19(2), 199-202.
Permanent Research Commons link: https://hdl.handle.net/10289/2681
The title compound was prepared from the (p-cymene)ruthenium chloride dimer and thioglycollic acid. The structure is a centrosymmetric dimer bridged by the soft-base S atoms, with the hard-base O atoms of the carboxylate group chelating to form a five-membered twisted-ring. The coordination of the ruthenium atoms is completed by a η6-p-cymene ligand, giving an 18-electron count. The Ru–S bonds are essentially equal at 2.396(1) Å.
This is the author's accepted version of an article published in the journal: Structural Chemistry. The original publication is available at www.springerlink.com.