Loading...
Thumbnail Image
Item

Tris(tert-butylisonitrile)hexacarbonyl- 3-ethylidyne-triangulo-tricobalt(I)(3 Co-Co)

Abstract
The title molecule, [Co3(C2H3)(C5H9N)3(CO)6] or [Co3(3-CCH3)(CNtBu)3(CO)6], lies on a threefold rotation axis. The three isonitrile ligands each occupy an equatorial site on each of the three Co atoms. The average Co-Co bond length is 2.4769 (6) Å. The tert-butyl groups are disordered over two orientations, with site occupancies of ca 0.6:0.4.
Type
Journal Article
Type of thesis
Series
Citation
Brown, J. M. & Nicholson, Brian K. (2007). Tris(tert-butylisonitrile)hexacarbonyl- 3-ethylidyne-triangulo-tricobalt(I)(3 Co-Co). Acta Crystallographica Section E: Structure Reports: Online, 63(10), 1-10.
Date
2007
Publisher
Blackwell Munksgaard
Degree
Supervisors
Rights
This is the electronic reprint version as authorised by the publisher.