The title compound, [As₄O₄(C₆H₄NO₃)₄], has an eight-membered As₄O₄ ring with a slightly twisted boat-chair conformation. The aryl groups complete the threefold coordination for each As atom. Each OH group forms a strong intramolecular O-H⋯O hydrogen bond to the adjacent NO₂ group, with only weak C-H⋯O, O⋯As [3.036 (6)-3.184 (6) Å] and O⋯O [2.921 (10)-2.930 (10) Å] interactions between tetramers.