(Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry

Nicholson, Brian K.; McIndoe, J. Scott; Clemente, Dore Augusto; Robinson, Ward T.

doi:10.1007/s11224-008-9308-9

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DOI

10.1007/s11224-008-9308-9

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Nicholson, B. K., Scott, J. M., Clemente, D. A. & Robinson, W. T. (2008). (Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry. Structural Chemistry, 19 (3), 489-492.

Permanent Research Commons link: https://hdl.handle.net/10289/2692

Abstract

There are two molecules in the asymmetric unit of the P2₁/c unit cell of ClCH₂Mn(CO)₅, the first halomethyl complex of manganese to be structurally determined. The molecules are crystallographically independent, despite an apparent local centre of symmetry. The average bond parameters include Mn–Calkyl 2.128(8) Å, C–Cl 1.811(8) Å and Mn–C–Cl 116.4(4)°

Date

2008

Type

Journal Article

Publisher

Springer

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This is an author’s accepted version of an article published in the journal: Structural Chemistry. The original publication is available at www.springerlink.com.

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