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      (Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry

      Nicholson, Brian K.; McIndoe, J. Scott; Clemente, Dore Augusto; Robinson, Ward T.
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      (Chloromethyl)pentacarbonylmanganese.pdf
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      DOI
       10.1007/s11224-008-9308-9
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      Nicholson, B. K., Scott, J. M., Clemente, D. A. & Robinson, W. T. (2008). (Chloromethyl)pentacarbonylmanganese(I): a crystal structure with a non-crystallographic centre of symmetry. Structural Chemistry, 19 (3), 489-492.
      Permanent Research Commons link: https://hdl.handle.net/10289/2692
      Abstract
      There are two molecules in the asymmetric unit of the P2₁/c unit cell of ClCH₂Mn(CO)₅, the first halomethyl complex of manganese to be structurally determined. The molecules are crystallographically independent, despite an apparent local centre of symmetry. The average bond parameters include Mn–Calkyl 2.128(8) Å, C–Cl 1.811(8) Å and Mn–C–Cl 116.4(4)°
      Date
      2008
      Type
      Journal Article
      Publisher
      Springer
      Rights
      This is an author’s accepted version of an article published in the journal: Structural Chemistry. The original publication is available at www.springerlink.com.
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      • Science and Engineering Papers [3122]
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