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      Tricyanovinylalkynyl–metal complexes: synthesis and some reactions

      Bruce, Michael I.; Burgun, Alexandre; Kramarczuk, Kathy A.; Nicholson, Brian K.; Parker, Christian R.; Skelton, Brian W.; White, Allan H.; Zaitseva, Natasha N.
      DOI
       10.1039/b810720c
      Link
       www.rsc.org
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      Citation
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      Bruce, M. I., Burgun, A., Kramarczuk, K. A., Nicholson, B. K., Parker, C. R., Skelton, B. W., White, A. H. & Zaitseva, N. N. (2008). Tricyanovinylalkynyl–metal complexes: synthesis and some reactions. Dalton Transactions, 7(1), 33-36.
      Permanent Research Commons link: https://hdl.handle.net/10289/2732
      Abstract
      Reactions of Group 8 metal ethynyls with tetracyanoethene afford tricyanovinylethynyl–metal derivatives, M{C≡CC(CN)=C(CN)2}(PP)Cp’ [2; M = Ru, Os; PP = (PPh3)2, dppe;Cp’=Cp,Cp*; not all combinations]; a similar reaction occurs with the vinylidene RuCl(=C=CHPh)(PPh3)Cp. Further replacement of a CNgroup in 2 occurs with nucleophiles, while homo- and hetero-metallic derivatives are obtained by coordination of one of the remaining CN groups to other metal–ligand fragments.
      Date
      2008
      Type
      Journal Article
      Publisher
      Royal Society of Chemistry
      Collections
      • Science and Engineering Papers [3077]
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