Arylstibonic acids [H₈(RSb)₁₂O₂₈]; precursors to organometallic isopolyoxostibonates [Na₂H₉(RSb)₁₂O₃₀]-, (R = aryl).

Clark, Christopher J.; Nicholson, Brian K.; Wright, Cody Elvin

doi:10.1039/b816113e

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Clark, C. J., Nicholson, B. K. & Wright, C. E. (2009). Arylstibonic acids [H₈(RSb)₁₂O₂₈]; precursors to organometallic isopolyoxostibonates [Na₂H₉(RSb)₁₂O₃₀]-, (R = aryl). Chemical Communications, 8, 923-925.

Permanent Research Commons link: https://hdl.handle.net/10289/2733

Abstract

Electrospray ionisation mass spectrometry shows that arylstibonic acids, RSbO₃H₂, give rise to oxo-bridged clusters derived from [H₈(RSb)₁₂O₂₈] which act as inorganic crown ligands towards Na+ cations; structure determination of one derivative revealed a cage-like anion [Na₂H₉(p-O₂NC₆H₄Sb)₁₂O₃₀.4H₂O]-.

Date

2009

Type

Journal Article

Publisher

Royal Society of Chemistry

Rights

This is an author's accepted version of an article published in the Journal: Chemical Communications. Copyright The Royal Society of Chemistry 2009.

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