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      Identification of the water amidogen radical complex

      Ennis, Courtney P.; Lane, Joseph R.; Kjaergaard, Henrik G.; McKinley, Allan J.
      DOI
       10.1021/ja808109m
      Link
       pubs.acs.org
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      Citation
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      Ennis, C. P., Lane, J. R., Kjaergarrd, H. G. & McKinley, A. J. (2009). Identification of the water amidogen radical complex. Journal of the American Chemical Society, 131(4), 1358-1358.
      Permanent Research Commons link: https://hdl.handle.net/10289/2858
      Abstract
      The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.
      Date
      2009
      Type
      Journal Article
      Publisher
      American Chemical Society
      Collections
      • Science and Engineering Papers [3124]
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