Identification of the water amidogen radical complex
Citation
Export citationEnnis, C. P., Lane, J. R., Kjaergarrd, H. G. & McKinley, A. J. (2009). Identification of the water amidogen radical complex. Journal of the American Chemical Society, 131(4), 1358-1358.
Permanent Research Commons link: https://hdl.handle.net/10289/2858
Abstract
The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.
Date
2009Type
Publisher
American Chemical Society