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dc.contributor.authorXu, Xingling
dc.contributor.authorFong, S.W. Audi
dc.contributor.authorLi, Zhaohui
dc.contributor.authorLoh, Zhi-Heng
dc.contributor.authorZhao, Feng
dc.contributor.authorVittal, Jagadese J.
dc.contributor.authorHenderson, William
dc.contributor.authorKhoo, Soo-Beng
dc.contributor.authorHor, T.S. Andy
dc.coverage.spatialUnited Statesen_NZ
dc.date.accessioned2009-08-31T23:06:21Z
dc.date.available2009-08-31T23:06:21Z
dc.date.issued2002
dc.identifier.citationXu, X., Fong, S. W. A., Li, Z., Loh, Z., Zhao, F., Vittal, J. J., Henderson, W., Khoo, S. & Hor, T. S. A. (2002). Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt₂(μ-S)₂M] Core (M = Hg, Au), (41), 25, 6838-6845.en
dc.identifier.urihttps://hdl.handle.net/10289/2885
dc.description.abstractNovel electroactive multimetallic compounds based on the {Pt₂(μ₂-S)₂M} core, viz. [Pt₂(PPh₃)₄(μ₃-S)₂HgFc]PF₆ (1) [Fc = (η⁵-C₅H₄)Fe(η⁵-C₅H₅)] and [Pt₂(PPh₃)₄(μ₃-S)₂Hg₂Fc⁶](PF₆)₂ (2) [Fc⁶ = Fe(η⁵-C₅H₄)₂], have been synthesized under the guide of electrospray mass spectrometry. The electrochemistry of these ferrocene funtionalized compounds together with the reported [Pt₂(PPh₃)₄(μ₃-S)₂HgPPh₃](PF₆)₂ (3), [Pt₂(PPh₃)₄(μ₂-S)(μ₃-S)HgPh]PF₆ (4), and [Pt₂(PPh₃)₄(μ₂-S)(μ₃-S)AuPPh₃]PF₆ (5) have been investigated using cyclic voltammetry and DFT calculations. These results point to a prominent ligand-based oxidation.en
dc.language.isoen
dc.publisherAmerican Chemical Societyen_NZ
dc.rightsThis article is published in the Journal of Inorganic Chemistry. (c) 2002 American Chemical Societyen
dc.subjectheterometallic aggregatesen
dc.subjectelectrospray mass spectrometryen
dc.subjectoxidationen
dc.titleSynthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt₂(μ-S)₂M] Core (M = Hg, Au)en
dc.typeJournal Articleen
dc.identifier.doi10.1021/ic011181oen
dc.relation.isPartOfInorganic Chemistryen_NZ
pubs.begin-page6838en_NZ
pubs.elements-id28011
pubs.end-page6845en_NZ
pubs.issue25en_NZ
pubs.volume41en_NZ


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