Nucleophilicity of the selenide ligands in [Pt₂(μ-Se)₂ (PPh₃)₄]. Molecular assembly of a novel {In₂Pt₄Se₆} core

Yeo, Jeremy S.L.; Vittal, Jagadese J.; Henderson, William; Hor, T.S. Andy

doi:10.1016/S0022-328X(02)01707-2

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10.1016/S0022-328X(02)01707-2

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Yeo, J. S. L., Vittal, J. J., Henderson, W., & Hor, T. S. A. (2002). Nucleophilicity of the selenide ligands in [Pt₂(μ-Se)₂ (PPh₃)₄]. Molecular assembly of a novel {In₂Pt₄Se₆} core. Journal of Organometallic Chemistry, 659(1/2), 92-94.

Permanent Research Commons link: https://hdl.handle.net/10289/3393

Abstract

Lewis basic Pt₂(μ-Se)₂(PPh₃)₄reacts with In(ClO₄)₃ to give a rare platinum–indium selenido aggregate, {[Pt₂(μ₃-Se₂)₂(PPh₃)₄]₂In₂(μ-Se)₂}{ClO₄}₂. Single-crystal X-ray diffraction analysis revealed a hexametallic framework supported by a planar {In₂Se₂} square sandwiched by two {Pt₂Se₂} hinged butterfly moieties. This structure resembles that of the semiconducting anion [(Ga₆Se₁₄)10⁻] by having a common double-tetrahedra {M₂Se₆} core. The planar {M₂Se₂} ring also exists in other semiconductors like In4Se3 and TlSe.

Date

2002

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Journal Article

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Elsevier Science SA

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Science and Engineering Papers [2580]