Research Commons
      • Browse 
        • Communities & Collections
        • Titles
        • Authors
        • By Issue Date
        • Subjects
        • Types
        • Series
      • Help 
        • About
        • FAQs
        • Collection Policy
        • OA Mandate Guidelines
        • Guidelines FAQ
        • Contact Us
      • My Account 
        • Sign In
        • Register
      View Item 
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      •   Research Commons
      • University of Waikato Research
      • Science and Engineering
      • Science and Engineering Papers
      • View Item
      JavaScript is disabled for your browser. Some features of this site may not work without it.

      Nucleophilicity of the selenide ligands in [Pt₂(μ-Se)₂ (PPh₃)₄]. Molecular assembly of a novel {In₂Pt₄Se₆} core

      Yeo, Jeremy S.L.; Vittal, Jagadese J.; Henderson, William; Hor, T.S. Andy
      Thumbnail
      Files
      Henderson nucleophilicity.pdf
      224.4Kb
      DOI
       10.1016/S0022-328X(02)01707-2
      Find in your library  
      Citation
      Export citation
      Yeo, J. S. L., Vittal, J. J., Henderson, W., & Hor, T. S. A. (2002). Nucleophilicity of the selenide ligands in [Pt₂(μ-Se)₂ (PPh₃)₄]. Molecular assembly of a novel {In₂Pt₄Se₆} core. Journal of Organometallic Chemistry, 659(1/2), 92-94.
      Permanent Research Commons link: https://hdl.handle.net/10289/3393
      Abstract
      Lewis basic Pt₂(μ-Se)₂(PPh₃)₄reacts with In(ClO₄)₃ to give a rare platinum–indium selenido aggregate, {[Pt₂(μ₃-Se₂)₂(PPh₃)₄]₂In₂(μ-Se)₂}{ClO₄}₂. Single-crystal X-ray diffraction analysis revealed a hexametallic framework supported by a planar {In₂Se₂} square sandwiched by two {Pt₂Se₂} hinged butterfly moieties. This structure resembles that of the semiconducting anion [(Ga₆Se₁₄)10⁻] by having a common double-tetrahedra {M₂Se₆} core. The planar {M₂Se₂} ring also exists in other semiconductors like In4Se3 and TlSe.
      Date
      2002
      Type
      Journal Article
      Publisher
      Elsevier Science SA
      Rights
      This is an author’s accepted version of an article published in the Journal of Organometallic Chemistry. Copyright © 2002 Elsevier Science B.V. All rights reserved.
      Collections
      • Science and Engineering Papers [2624]
      Show full item record  

      Usage

      Downloads, last 12 months
      12
       
       
       

      Usage Statistics

      For this itemFor all of Research Commons

      The University of Waikato - Te Whare Wānanga o WaikatoFeedback and RequestsCopyright and Legal Statement