dc.contributor.author | Henderson, William | |
dc.contributor.author | Alley, Steven R. | |
dc.date.accessioned | 2009-11-20T01:35:54Z | |
dc.date.available | 2009-11-20T01:35:54Z | |
dc.date.issued | 2002 | |
dc.identifier.citation | Henderson, W., & Alley, S. R. (2002). Ferrocenyl hydroxymethylphosphines (η⁵-C₅H₅)Fe[η⁵⁻C₅H₄P(CH₂OH)₂] and 1,1′-[Fe{η⁵-C₅H₄P(CH₂OH)₂}₂] and their chalcogenide derivatives. Journal of Organometallic Chemistry, 658(1/2), 181-190. | en |
dc.identifier.uri | https://hdl.handle.net/10289/3403 | |
dc.description.abstract | The ferrocenyl hydroxymethylphosphines FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵⁻C₅H₄)₂] were prepared by reactions of the corresponding primary phosphines FcPH₂ and 1,1′-Fc′(PH₂)₂ with excess aqueous formaldehyde. The crystal structure of FcP(CH₂OH)₂ was determined and compared with the known ferrocenyl hydroxymethylphosphine FcCH₂P(CH₂OH)₂. The chalcogenide derivatives FcP(E)(CH₂OH)₂ and 1,1′-Fc′[P(E)(CH₂OH)₂]₂ (E=O, S, Se) were prepared and fully characterised. Crystal structure determinations on FcP(O)(CH₂OH)₂ and FcP(S)(CH₂OH)₂ were performed, and the hydrogen-bonding patterns are compared with related compounds. The sulfide shows no hydrogen-bonding involving the phosphine sulfide group, in contrast to other reported ferrocenyl hydroxymethylphosphine sulfides. The platinum complex cis-[PtCl₂{FcP(CH₂OH)₂}₂] was prepared by reaction of 2 mol equivalents of FcP(CH₂OH)₂ with [PtCl₂(1,5-cyclo-octadiene)], and was characterised by 31P-NMR spectroscopy and negative ion electrospray mass spectrometry, which gave a strong [M+Cl]⁻ ion. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | en | |
dc.publisher | Elsevier Science SA | en_NZ |
dc.rights | This is an author’s accepted version of an article published in the Journal of Organometallic Chemistry. Copyright © 2002 Elsevier Science B.V. All rights reserved. | en |
dc.subject | chemistry | en |
dc.subject | ferrocenyl | en |
dc.title | Ferrocenyl hydroxymethylphosphines (η⁵-C₅H₅)Fe[η⁵⁻C₅H₄P(CH₂OH)₂] and 1,1′-[Fe{η⁵-C₅H₄P(CH₂OH)₂}₂] and their chalcogenide derivatives | en |
dc.type | Journal Article | en |
dc.identifier.doi | 10.1016/S0022-328X(02)01651-0 | en |
dc.relation.isPartOf | Journal of Organometallic Chemistry | en_NZ |
pubs.begin-page | 181 | en_NZ |
pubs.elements-id | 28269 | |
pubs.end-page | 190 | en_NZ |
pubs.issue | 1-2 | en_NZ |
pubs.volume | 658 | en_NZ |
uow.identifier.article-no | PII S0022-328X(02)01651-0 | en_NZ |