Show simple item record  

dc.contributor.authorHenderson, William
dc.contributor.authorAlley, Steven R.
dc.date.accessioned2009-11-20T01:35:54Z
dc.date.available2009-11-20T01:35:54Z
dc.date.issued2002
dc.identifier.citationHenderson, W., & Alley, S. R. (2002). Ferrocenyl hydroxymethylphosphines (η⁵-C₅H₅)Fe[η⁵⁻C₅H₄P(CH₂OH)₂] and 1,1′-[Fe{η⁵-C₅H₄P(CH₂OH)₂}₂] and their chalcogenide derivatives. Journal of Organometallic Chemistry, 658(1/2), 181-190.en
dc.identifier.urihttps://hdl.handle.net/10289/3403
dc.description.abstractThe ferrocenyl hydroxymethylphosphines FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵⁻C₅H₄)₂] were prepared by reactions of the corresponding primary phosphines FcPH₂ and 1,1′-Fc′(PH₂)₂ with excess aqueous formaldehyde. The crystal structure of FcP(CH₂OH)₂ was determined and compared with the known ferrocenyl hydroxymethylphosphine FcCH₂P(CH₂OH)₂. The chalcogenide derivatives FcP(E)(CH₂OH)₂ and 1,1′-Fc′[P(E)(CH₂OH)₂]₂ (E=O, S, Se) were prepared and fully characterised. Crystal structure determinations on FcP(O)(CH₂OH)₂ and FcP(S)(CH₂OH)₂ were performed, and the hydrogen-bonding patterns are compared with related compounds. The sulfide shows no hydrogen-bonding involving the phosphine sulfide group, in contrast to other reported ferrocenyl hydroxymethylphosphine sulfides. The platinum complex cis-[PtCl₂{FcP(CH₂OH)₂}₂] was prepared by reaction of 2 mol equivalents of FcP(CH₂OH)₂ with [PtCl₂(1,5-cyclo-octadiene)], and was characterised by 31P-NMR spectroscopy and negative ion electrospray mass spectrometry, which gave a strong [M+Cl]⁻ ion.en
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherElsevier Science SAen_NZ
dc.rightsThis is an author’s accepted version of an article published in the Journal of Organometallic Chemistry. Copyright © 2002 Elsevier Science B.V. All rights reserved.en
dc.subjectchemistryen
dc.subjectferrocenylen
dc.titleFerrocenyl hydroxymethylphosphines (η⁵-C₅H₅)Fe[η⁵⁻C₅H₄P(CH₂OH)₂] and 1,1′-[Fe{η⁵-C₅H₄P(CH₂OH)₂}₂] and their chalcogenide derivativesen
dc.typeJournal Articleen
dc.identifier.doi10.1016/S0022-328X(02)01651-0en
dc.relation.isPartOfJournal of Organometallic Chemistryen_NZ
pubs.begin-page181en_NZ
pubs.elements-id28269
pubs.end-page190en_NZ
pubs.issue1-2en_NZ
pubs.volume658en_NZ
uow.identifier.article-noPII S0022-328X(02)01651-0en_NZ


Files in this item

This item appears in the following Collection(s)

Show simple item record