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dc.contributor.authorHenderson, William
dc.contributor.authorNicholson, Brian K.
dc.contributor.authorDevoy, Sarah M.
dc.contributor.authorHor, T.S. Andy
dc.date.accessioned2009-11-24T22:22:19Z
dc.date.available2009-11-24T22:22:19Z
dc.date.issued2008
dc.identifier.citationHenderson, W., Nicholson, B. K., Devoy, S. M., & Hor, T. S. Andy. (2008). Dinuclear sulfide–thiolate complexes [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ as cationic metalloligands. Inorganica Chimica Acta, 361(7), 1908-1914.en
dc.identifier.urihttps://hdl.handle.net/10289/3413
dc.description.abstractThe cationic monoalkylated derivatives of the well-known metalloligand [Pt₂(μ-S)₂(PPh₃)₄], viz. [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ (R = n-Bu, CH₂Ph) are themselves able to act as metalloligands towards the Ph₃PAu⁺ and R′Hg⁺ (R′ = Ph or ferrocenyl) fragments, by reaction with Ph₃PAuCl or R′HgCl, respectively. The resulting dicationic products [Pt₂(μ-SR)(μ-SAuPPh₃)(PPh₃)₄]²⁺ and [Pt₂(μ-SR)(μ-SHgR′)(PPh₃)₄]²⁺ are readily isolated as their hexafluorophosphate salts, and have been fully characterised by spectroscopic techniques and an X-ray structure determination on [Pt₂(μ-SR)(μ-SHgFc)(PPh₃)₄](PF₆)₂.en
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.publisherElsevieren_NZ
dc.rightsThis is an author’s accepted version of an article published in the journal: Inorganica Chimica Acta. Copyright © 2007 Elsevier B.V. All rights reserved.en
dc.subjectplatinum complexesen
dc.subjectthiolate complexesen
dc.subjectsulfide complexesen
dc.subjectcrystal structureen
dc.subjectelectrospray mass spectrometryen
dc.subjectmetalloliganden
dc.titleDinuclear sulfide–thiolate complexes [Pt₂(μ-S)(μ-SR)(PPh₃)₄]⁺ as cationic metalloligandsen
dc.typeJournal Articleen
dc.identifier.doi10.1016/j.ica.2007.10.003en
dc.relation.isPartOfInorganica Chimica Actaen_NZ
pubs.begin-page1908en_NZ
pubs.elements-id32933
pubs.end-page1914en_NZ
pubs.issue7en_NZ
pubs.volume361en_NZ


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